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Nonionic Film-forming Polymer of Vinylpyrrolidone with Vinyl Acetate VA Copolymers
Cosmetic Thickeners

VP/VA Copolymers

VP/VA Copolymer is a Vinylpyrrolidone/vinyl acetate copolymer, a nonionic film-forming polymer for hair care applications. It is a white powder with a slight characteristic odor.VP/VA Copolymer is used in hair care and styling products as a fixative and film-forming agent. It has exceptional properties both for aerosol sprays (hairsprays) and non-aerosol products like liquid setting lotions, gels, and mousses.

  • Product Name: Copolymer of Vinylpyrrolidone with Vinyl Acetate
  • INCI Name: VP/VA Copolymer
  • CAS No.: 25086-89-9
  • Formula: (C6H9NO·C4H6O2)x
  • Functions: Binder, Film-forming agent, Fixative, Hair conditioning

VP/VA Copolymer is a Vinylpyrrolidone/vinyl acetate copolymer, a nonionic film-forming polymer for hair care applications.PVP VA Copolymer is a water-soluble polymer resin. It is an odorless, non-toxic, non-irritant white powder or transparent solution; soluble in water, alcohols, amines and other organic solvents; it has good adhesion, moisture absorption, film formation, and surface activity; the solutions formed copolymer by PVP VA in water range from clear to turbidite. The degree of turbidity depends on the ratio of vinylpyrrolidone to vinyl acetate, and the solution is slightly acidic but not electrolytic.

The solubility in water depends on the proportion of vinyl-pyrrolidone (increasing vinylpyrrolidone content makes it more hygroscopic); the solution is clear, almost colorless to slightly yellowish. VP/VA Copolymer is soluble in ethanol or isopropanol.

内容插图 PVP VA Series 1

VP/VA Copolymer is used in hair care and styling products as a fixative and film-forming agent. It has exceptional properties both for aerosol sprays (hairsprays) and non-aerosol products like liquid setting lotions, gels, and mousses.

内容插图 PVP VA Series 2

For the cosmetics made of PVP VA, ‌such as hair spray and mousse, compared with those made of natural shellac, has the advantages of good luster, strong elasticity, easy combing, non-brittle, ‌non-stick and comfortable after use. 

For example, in hair fixing agent raw materials, the addition of ‌PVP VA can significantly enhance the hair fixing effect, at the same time to maintain a good feeling. When mixed with PVP-K30, it can enhance the effect of fixed hair.

VP/VA Copolymer is a versatile ingredient prized for its excellent film-forming and adhesive properties. In cosmetics, it is a key component in hairsprays and styling gels, providing strong, flexible hold with humidity resistance. It also enhances the long-lasting wear and water resistance of mascaras and sunscreens.

Key Technical Parameters

Cosmetic Grade VP/VA Copolymers

Product PVP/VA 64 Powder PVP/VA 64W PVP/VA 73W
Appearance White to creamy white,free-flowing powder Transparent to slight yellowish liquid
VP/VA 60/40 60/40 70/30
K Value 27-35 27~35 27~35
Monomers 0.1% max. 0.1% max. 0.1% max.
Water 5.0% max. 48~52% 48~51%
Solid Content 95% max. 48~51% 48~52%
Sulphated Ash 0.1% max. 0.1% max. 0.1% max.
pH Value(10% in water) 4.0~7.0 4.0~7.0 4.0~7.0

Pharmaceutical Grade VP/VA Copolymer-Copovidone

Appearance White or yellowish-white powder or flakes,hygroscopic
Viscosity(Express as K Value) 25.20~30.24
Solubility Freely soluble in water,in alcohol and in methylene chloride
Identifications A.Infrared Absorption
  B.A red colour appears
  C.A violet colour appears
Peroxides(Expressed as H2O2) 400 ppm max.
Hydrazine 1 ppm max.
Monomers(VP+VA) 0.1% max.
Impurity A(2-Pyrrolidone) 0.5% max.
Heavy Metals(as Pb) 20 ppm max.
Loss on Drying 5.0% max.
Sulphated Ash 0.1% max.
Ethenyl Acetate Content 35.3~42.0% max.
Nitrogen Content 7.0~8.0 %

Technical Grade VP/VA Copolymers

Product PVP/VA 64 Powder PVP/VA 64W PVP/VA 73W
Appearance White to creamy white,free-flowing powder Transparent to slight yellowish liquid
VP/VA 60/40 60/40 70/30
K Value 27-35 27~35 27~35
Monomers 0.2% max. 0.2% max. 0.2% max.
Water 5.0% max. 48~52% 48~51%
Solid Content 95% max. 48~51% 48~52%
Sulphated Ash 0.1% max. 0.1% max. 0.1% max.
pH Value(10% in water) 4.0~7.0 4.0~7.0 4.0~7.0

Within the pharmaceutical industry, this polymer serves as a binder in tablets and creates protective, easy-to-swallow coatings for pills. It is also used in controlled-release drug delivery systems to manage how quickly medication is absorbed.

内容插图 PVP VA Series 3

Beyond these fields, VP/VA Copolymer finds application in industrial adhesives, creating removable glues, and as a binding agent in coatings and inks, showcasing its remarkable versatility.

Applications

Film formers

 Personal Care Products

 Hair care products

● Pharmaceutical industry

Advantages

Good stabilization

Good compatibility

Good solubility

● Biological compatibility

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